Crosslighting
I was just messing around a little with some lighting stuff on the Strobist blog I really like how it makes the subject look 3D. I can't wait to do some of these with some better landscapes then the side yard. No Photoshop done, just basic contrast and WB. If you want to check out how to do this see this post about cross lighting on the Stobist blog. Just pick an easier subject then a 2yr little girl =)